Now a days getting DDC number for books is not hard job. There are several online library catalog, from where any body may collect his required DDC number. Some links are:

On 3/22/07, N.S. Harinarayana <ns.harinarayana@gmail.com> wrote:

This has a reference to Divya Singh's query.
As DDC is a priced publication, one may not get the whole schedules for free access. Visit http://www.oclc.org/dewey/ for more information.

However, if one wants DDC numbers for some specific titles, one can find them in LOC catalogue ( http://catalog.loc.gov/)
--
N.S. Harinarayana, Ph.D
Department of Library and Information Science
University of Mysore, Manasagangtori
Mysore 570 006
Off. Ph: (0821) 2419393
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